Nucleophilic substitution reaction at the 1-position of 1-hydroxytryptamine and -tryptophan derivatives
スポンサーリンク
概要
- 論文の詳細を見る
A novel nucleophilic substitution reaction at the 1-position of indole nucleus was discovered by reacting 1-hydroxytryptamine and -tryptophan derivatives with indoles in 85% formic acid yielding 1-(indol-3-yl)indoles. Their structures were determined by X-Ray crystallographic analysis and chemical correlations. An SN2 mechanism on the indole nitrogen (1-position) is proposed.
- 日本複素環化学研究所の論文
- 2003-12-31
日本複素環化学研究所 | 論文
- Reactions of 2-Triphenylphosphoimino-1-azaazulenes with Aryl Isocyanates and Aryl Isothiocyanates
- Synthesis and some reactions of 11-azacyclohept[a]azulen-3(3H)-ones and evaluation of their cytotoxic activity against HeLa S3 cells
- Palladium-catalyzed heteroarylamination of ethyl 2-chloro-1-azaazulene-3-carboxylate and annulation of heteroarylamino-1-azaazulenes
- Synthesis of [poly(2-pyridyl)-substituted]-1-azaazulenes
- Heteroarylamination and heteroarylsulfidation of 2-chloro-1-azaazulenes