エピクロルヒドリンと水酸化ナトリウムの反応と生成重合体について

概要

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The reaction mechanism of the polymerization of epichlorhydrin catalyzed with sodium hydroxide，was being researched in connection with the following results: the generation of acetylene and hydrogen throughout the polymerization，the ESR spectrum of the active species in reacting process，and the same polymerization of epichlorhydrin. The polymerizations　of epichlorhydrin， catalyzed with　sodium hydroxide， were　being made to find out the polymerization condition under which the obtained polymer will serve as an adsorbent. The polymerization was examined by taking account of reaction temperature， atomosphere， pressure and the amount of sodium hydroxide， an in relation to the adsorption of acetic acid and methylene blue from aqueous solutions. The column of the obtained polymer was effective for the chromatographic separation of the components of a natural pigment. The surface of the obtained polymer was　also shown under electron micrograph.
北見工業大学の論文