2c04 有機金属錯体のディスコティック液晶(108) : 3本のアルコキシ鎖を導入したフェノキシ基置換フタロシアニン-フラーレン複合体の合成と液晶性(物理・物性,口頭発表,2012年日本液晶学会討論会)

概要

論文の詳細を見る
Previously, we prepared the phthalocyaninato copper(II) complexes substituted by eight p, m, m'-trialkoxyphenoxy groups, abbreviated as [(C_nO)_3PhO]_8PcCu, which show a wide temperature range of Cubic mesophase irrespective of a disk-like molecule. Cubic phases are still unclear and fascinating mesophases. There have been only four examples showing Cubic phases in discotic liquid crystals including this [(C_<14>O)_3PhO]_8PcCu complexes. In this work, we have successfully synthesized a novel phthalocyanine-fullerene dyad, [(C_<14>O)_3PhO]_6PcCu-C_<60>(1), and investigated the mesomorphism.
日本液晶学会の論文
2012-08-20