C205 EFFECTS OF TEMPERATURE ON DIRECT CARBON FUEL CELL ANODE REACTION CHARACTERISTICS(Fuel Cell-1)
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概要
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The reaction characteristics of direct carbon fuel cell (DCFC) were investigated experimentally by controlling button cell temperature at 750〜900℃ and carbon fuel temperature at 800〜950℃. The polarization curves, electrochemical impedance spectra and anode gas compositions were measured during testing. The results showed that raising the temperatures of both button cell and carbon fuel can improve the performance of DCFC significantly. By increasing the carbon fuel temperature, the gasification reaction rate of carbon fuel can be accelerated and the polarization of DCFC can be reduced. The gasification of carbon fuel was the limitation factor of DCFC performance. The ohmic resistance and the activation polarization decrease with increasing of button cell temperature. The carbon deposition has been observed after testing, which can be reduced at higher temperature according to thermal dynamic analysis. In addition, it was deduced that the disordered carbon in carbon fuel is more active from Raman spectra.
- 一般社団法人日本機械学会の論文
- 2009-11-16
著者
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Li Chen
Key Laboratory For Thermal Science And Power Engineering Of Ministry Of Education Department Of Ther
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Li Chen
Key Lab Of Analytical Chemistry For Life Science Ministry Of Education School Of Chemistry And Chemi
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Cai Ningsheng
Key Laboratory For Thermal Science And Power Engineering Of Ministry Of Education Department Of Ther
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SHI Yixiang
Key laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of The
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Shi Yixiang
Key Laboratory For Thermal Science And Power Engineering Of Ministry Of Education Department Of Ther
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- C205 EFFECTS OF TEMPERATURE ON DIRECT CARBON FUEL CELL ANODE REACTION CHARACTERISTICS(Fuel Cell-1)