25pD05 Ru-ヘテロ原子結合をアンカーとして利用した結合切断反応と分子変換プロセスへの応用(ナノ機能材料(1),第34回結晶成長国内会議)

概要

論文の詳細を見る
Reaction of RuClCp(PPh_3)_3 (1) [Cp = cyclopentadienyl] with potassium 2-allylphenoxide gave RuCp[η^3-CH_2CHCHC_6H_4OH-2](PPh_3) (4), which would be formed Ru-O bond followed by C-H bond activation of ortho-allyl moiety. Ru(η^4-COT)(PEt_3)_3 (5) [COT = 1,3,5-cyclooctatriene] dehydrogenated allylalcohol to give Ru(η^4-acrolein)(PEt_3)_3 (6), which is interesting as an supposed intermediate for isomerization of allylic alcohols to carbonyl compounds.
日本結晶成長学会の論文
2004-08-25