0513 C6およびC7ナフテンを用いた水素貯蔵システム設計のための平衡物性測定(S49-1 水素貯蔵およびPEM燃料電池,S49 燃料電池技術)

概要

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To design a fuel cell system, solid-liquid equilibrium was measured for two binaries, benzene + toluene, benzene + methylcyclohexane, and a quaternary, benzene + cyclohexane + methylcyclohexane + toluene, by use of a cooling type apparatus. Hydrogen (H_2) solubility was also measured for four binaries, benzene + toluene, cyclohexane + methylcyclohexane, benzene + methylcyclohexane and cyclohexane + toluene, and a quaternary, benzene + cyclohexane + methylcyclohexane + toluene, by use of a synthetic type apparatus up to 5.000MPa at 303.15K. The H_2 solubility was increased linearly with the pressure following the Henry's law for all systems. Using the optimized binary interaction parameters, cubic equation of states well predicted the H_2 solubility for the quaternary.
社団法人日本機械学会の論文
2007-09-07