Direct Three-Dimensional Observations of Order-Order Transition from Gyroid to Cylindrical Structures in a Block Copolymer(Non Equilibrium Soft Matter)
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概要
- 論文の詳細を見る
An order-order transition (OOT) from the bicontinuous double-gyroid (G) structure to the hexagonally-packed cylindrical (C) structure in a poly(styrene-block-isoprene) (SI) block copolymer was investigated by transmission electron microtomography (TEMT). The coexistence of the G and C microdomains during the OOT was observed. The boundary structures between the G and C microdomains were directly three-dimensionally visualized. It was found that the {220} plane of the G structure changed to the {110} plane of the newly-generated C structure, consistent with Matsen's prediction from his computer simulations based on self-consistent field (SCF) theory.
- 理論物理学刊行会の論文
- 2008-12-05
著者
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Jinnai Hiroshi
Department Of Macromolecular Science And Engineering Graduate School Of Science And Engineering Kyot
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Sugimori Hidekazu
Department Of Macromolecular Science And Engineering Graduate School Of Science And Engineering Kyot
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Kaneko Takeshi
Department Of Internal Medicine And Clinical Immunology Yokohama City University Graduate School Of
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NIIHARA Ken-ichi
Department of Macromolecular Science and Engineering, Graduate School of Science and Engineering, Ky
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MIYOSHI Wakana
Department of Macromolecular Science and Engineering, Graduate School of Science and Engineering, Ky
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Jinnai Hiroshi
Department Of Macromolecular Science And Engineering Graduate School Of Science And Engineering Kyot
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Miyoshi Wakana
Department Of Macromolecular Science And Engineering Graduate School Of Science And Engineering Kyot
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Niihara Ken-ichi
Department Of Macromolecular Science And Engineering Graduate School Of Science And Engineering Kyot
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Kaneko Takeshi
Department Of Macromolecular Science And Engineering Graduate School Of Science And Engineering Kyot
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JINNAI Hiroshi
Institute for Materials Chemistry and Engineering, Kyushu University
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Sugimori Hidekazu
Department of Macromolecular Science and Engineering, Graduate School of Science and Engineering, Kyoto Institute of Technology
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KANEKO Takeshi
Department of Macromolecular Science and Engineering, Graduate School of Science and Engineering, Kyoto Institute of Technology
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MIYOSHI Wakana
Department of Macromolecular Science and Engineering, Graduate School of Science and Engineering, Kyoto Institute of Technology
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