D-11 KINETIC STUDIES OF THE RING-OPENING BULK POLYMERIZATION OF ε-CAPROLACTONE BY DILATOMETRY(Session: Polymer/Wear)

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概要

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• Dilatometry is the technique most often used for studying the kinetics of polymerization by following the volume change which accompanies polymer formation. In this work, the kinetics of the ring-opening bulk polymerization of ε-caprolactone at 140 ℃ using 0.1 mol% stannous hexoxide as a novel initiator were studied. After a prolonged induction period, the results showed a close adherence to first-order kinetics with respect to monomer with a first-order rate constant, k_1, of 4.00×10^<-2> min^<-1>.

• 一般社団法人日本機械学会の論文
• 2006-11-08

著者

• Molloy Robert

  Biomedical Polymers Technology Unit Department Of Chemistry Faculty Of Science Chiang Mai University

• Kleawkla Achara

  Biomedical Polymers Technology Unit, Department of Chemistry, Faculty of Science, Chiang Mai Univers

• Naksata Wimol

  Biomedical Polymers Technology Unit, Department of Chemistry, Faculty of Science, Chiang Mai Univers

• Punyodom Winita

  Biomedical Polymers Technology Unit, Department of Chemistry, Faculty of Science, Chiang Mai Univers

• Naksata Wimol

  Biomedical Polymers Technology Unit Department Of Chemistry Faculty Of Science Chiang Mai University

• Punyodom Winita

  Biomedical Polymers Technology Unit Department Of Chemistry Faculty Of Science Chiang Mai University

• Kleawkla Achara

  Biomedical Polymers Technology Unit Department Of Chemistry Faculty Of Science Chiang Mai University

関連論文

• D-11 KINETIC STUDIES OF THE RING-OPENING BULK POLYMERIZATION OF ε-CAPROLACTONE BY DILATOMETRY(Session: Polymer/Wear)
• Kinetic Studies of the Ring-Opening Bulk Polymerization of .EPSILON.-Caprolactone Using a Novel Tin(II) Alkoxide Initiator

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