50 TOTAL SYNTHESIS OF THE PRELOG-DJERASSI LACTONE AND METHYNOLIDE

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概要

• 論文の詳細を見る

• Lactone 11 and trans-vinyl iodide 3, which represent the C(1) to C(7) and C(8) to C(11) fragments of methynolide, respectively, have been synthesized and linked. Adduct 21 has been transformed into (±)-seco-acid 24 which previously had been converted into methynolide by Masamune. Oxidation of lactone 11, available in both optically active and racemic forms, provided enantiomerically pure and racemic Prelog-Djerassi lactone (2).

• 天然有機化合物討論会の論文
• 1979-09-20

著者

• Ohfune Yasufumi

  ピッツバーグ大

• Grieco Paul

  ピッツバーグ大

• Yokoyama Yuusaku

  ピッツバーグ大

• Owens William

  ピッツバーグ大

関連論文

• 50 TOTAL SYNTHESIS OF THE PRELOG-DJERASSI LACTONE AND METHYNOLIDE

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