17 マタタビに含まれるC-11およびC-13テルペンの化学

概要

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In previous paper we reported the structure of actinidiolide(I) dihydroactinidiolide(II) and actinidol(III), the odd terpenes from Actinidia polygama Mig.. Recently, much attention has been devoted to dihydroactinidiolide because of its isolation from several species of plants as the principle of tea flavor. We herein report the simple synthetic route to dihydroactinidiolide, the biogenetic type synthesis of dihydroactinidiolide, actinidiolide and actinidol and the formation of allenic compound (VII) from β-ionol by photosensitized oxidation. The significance of photosensitized oxidation in the biogenesis of C-11 and C-13 terpenes was demonstrated.
天然有機化合物討論会の論文
1968-09-20