Synthesis of ceramic nanoparticles with non-equilibrium crystal structures and chemical compositions by controlled thermal plasma processing(The 61th CerSJ Awards for Academic Achievement in Ceramic Science and Technology : Review)
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概要
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The synthesis of functional nanostructured powders has been developed through reactive thermal plasma processing. Nanosized particles of titanium oxide powder with high crystallinity and non-equilibrium chemical composition were synthesised by onestep processing based on the oxidation of solid and liquid precursors. Spherical carbon powders were treated in a reactive thermal plasma. Crystallinity, chemical composition, and surface morphology were changed in plasma-treated carbon powders. Plasma-treated carbon powders were used as the anode of a lithium-ion rechargeable battery, and improvements in discharge capacity and efficiency were recognized. The generation of pulse-modulated RF inductively coupled plasmas (PM-ICPs) was developed for the first time. The non-equilibrium states were recognized at the instances of pulse-on and pulse-off, and the concentration of chemically active radical species was increased. This offers a unique physico-chemical condition for materials processing.
- 社団法人日本セラミックス協会の論文
- 2008-03-01
著者
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Ishigaki Takamasa
Graduate School Of Engineering Hosei Univ.
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Ishigaki Takamasa
Plasma Processing Group Nano Ceramics Center National Institute For Materials Science
関連論文
- Synthesis of Ceramic Materials Using High-Temperature Thermal Plasma
- Synthesis of ceramic nanoparticles with non-equilibrium crystal structures and chemical compositions by controlled thermal plasma processing(The 61th CerSJ Awards for Academic Achievement in Ceramic Science and Technology : Review)