Chelate Complexes of Nickel (II) and Copper (II) with trans-1, 2-Diaminocyclohexane

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概要

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• Several nickel chelates with trans-1, 2-diaminocyclohexane (=cyclohexanediamine ; abbreviated as chxn), Ni chxn_2X_2・nH_2O (X=Cl, Br, NO_3 or ClO_4 ; n=0 or 2) and Ni chxn_3X_2・nH_2O (X=Cl, Br or NO_3 ; n=1 or 2.5) were prepared, together with some copper (II) chelates with the same ligand, Cu chxn_2(NO_3)_2 and Cu chxn L (NO_3)_2・nH_2O (L=2, 2'-bipyridine : bip or 1, 10-phenanthroline : phen ; n=0 or 1). Two types of the bis-chxn nickel complexes are obtained, one is yellow diamagnetic and square planar [Ni chxn_2]X_2 and the other, purple, paramagnetic and octahedral [Ni chxn_2(H_2O)_2]X_2. These two chelates are in equilibrium in the aqueous solution.

著者

• Tsuchida Masako

  Department Of Bioinformatics Graduate School Of Engineering Soka University

• Tsuchida Masako

  Department Of Chemistry Faculty Of Science Ochanomizu University(present Office):department Of Chemi

関連論文

• Chelate Complexes of Nickel (II) and Copper (II) with trans-1, 2-Diaminocyclohexane
• 2P-178 新規イネキネシンE15の精製と特徴付け(分子モーター(2),第46回日本生物物理学会年会)

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