Metacyclophanes and Related Compounds. XXV. Generation of Bis (o-quinone methide) from [2.2] Metacyclophane Having Spiro Skeleton and Its Reactions with Alcohols, Acetic Acid, and Ethenes

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概要

• 論文の詳細を見る

• Spiro compound 3 obtained in the oxidation of 8,16-dihydroxy[2.2]meta-cyclopnane 2 with Ag_2O, readily generated bis(o-quinone methide) 4 on mild heating, which was trapped with methanol, ethanol, acetic acid to give di-arylethane 5. [4+2]Cycloadduct 9 of 4 and ethene 8 was obtained when 3 was thermolyzed in the presence of 8 in refluxing benzene.

• 九州大学の論文
• 1989-09-30

著者

• YAMATO Takehiko

  Department of Applied Chemistry, Faculty of Science and Engineering, Saga University

• Yamato Takehiko

  Department Of Industrial Chemistry Faculty Of Science And Engineering Saga University

• Yamato Takehiko

  Department Of Applied Chemistry Faculty Of Science And Engineering Saga University

• KAJIHARA Masami

  Department of Industrial Chemistry, Faculty of Science and Engineering, Saga University

• MATSUMOTO Jun-ichi

  Department of Industrial Chemistry, Faculty of Science and Engineering, Saga University

• TORII Akiyoshi

  Kurume College of Technology

• Torii Akiyoshi

  Kurume National College Of Technology

• Yamato T

  Kyushu Univ.

• Kajihara Masami

  Department Of Industrial Chemistry Faculty Of Science And Engineering Saga University

• Matsumoto Jun-ichi

  Department Of Industrial Chemistry Faculty Of Science And Engineering Saga University

関連論文

• Potassium-Selective Membrane Electrodes Based on Macrocyclic Metacyclophanes Analogous to Calixarenes
• Evaluation of Transannular Interaction in [2.3]Metacyclophanes
• Preparation of 1,2-Diaminopyrene via a 1,2,5-Thiadiazole Route
• Metacyclophanes and Related Compounds. XXV. Generation of Bis (o-quinone methide) from [2.2] Metacyclophane Having Spiro Skeleton and Its Reactions with Alcohols, Acetic Acid, and Ethenes
• Reversible Optical Rotation Change According to the Enantiospecific Photochromic Reaction of [2.2]Metacyclophan-1-ene
• Metacyclophanes and Related Compounds. 20. Reaction of Methyl [2.2] metacyclophanes with N-Bromosuccinimide
• Reaction of 3,4-Diaroyl-1,2,5-oxadiazole-2-oxide with Hydrazine Hydrate

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