ジアルキルエーテル類の電解酸化

概要

論文の詳細を見る
The anodic oxidation processes of dialkylethers in perchloric acid solution have been studied on the basis of analyses of products. The results obtained are as follows.　(1) The main products are alcohol and aldehyde (or ketone) corresponding to carbon number of alkyl radicals consisting of the ethers One of the two alkyl radicals is oxidized to alcohol, another gives aldehyde.　(2) The oxidation processes are the reaction via α-cation of the ethers formed by two electron transfer and deprotonation in α-position, and then alkyl cation may be considered to be formed through the α-cation.　(3) In the case of unsymmetrical dialkylethers, the deprotonation occurs in methyl radical if one of two alkyl radicals is methyl radical. The deprotonation in ethylbutylether, however, is observed in both two alkyl radicals, but it is easy to occur in ethyl radical having a minor carbon number.
山形大学の論文
1979-02-20