Synthesis, Crystal Structure, and DNA-Binding Study on the Trinitrate{2,2'-[2,3-naphthylenebis(oxy)]-bis(N,N-diisopropyl(acetamide))} Gadolinium(III) Complex

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概要

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• A 2,2'-[2,3-naphthylenebis(oxy)]-bis(N,N-diisopropyl(acetamide)) ligand (L) and its Gd(III) complex have been prepared and characterized. The crystal and molecular structure of the complex was determined by single-crystal X-ray diffraction. The interactions of complex with calf thymus DNA were investigated by UV-vis, fluorescence and viscosity measurements. Experimental results indicated that the complex can bind to DNA by intercalation modes. Its intrinsic binding constant is 1.03×10^6M^<-1>.

• 公益社団法人日本薬学会の論文
• 2006-08-01

著者

• Huang Xiaofeng

  Department Of Chemistry And State Key Laboratory Of Applied Organic Chemistry Lanzhou University

• Liu Weisheng

  Department Of Chemistry And State Key Laboratory Of Applied Organic Chemistry Lanzhou University

• Liu Weisheng

  Department Of Chemistry And Natioinal Laboratory Of Applied Organic Chemistry Lanzhou University

• LEI Kewei

  Department of Chemistry and State Key Laboratory of Applied Organic Chemistry, Lanzhou University

• WANG Daqi

  Department of Chemistry, Liaocheng University

• Wang Daqi

  Department Of Chemistry Liaocheng University

• Lei Kewei

  Department Of Chemistry And State Key Laboratory Of Applied Organic Chemistry Lanzhou University

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• Synthesis, Crystal Structure, and DNA-Binding Study on the Trinitrate{2,2'-[2,3-naphthylenebis(oxy)]-bis(N,N-diisopropyl(acetamide))} Gadolinium(III) Complex
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