Scandium-Catalyzed Carbon-Carbon Bond Formations Using α-Organosulfanyl and Organoselanyl-α-fluoroacetic Acid Derivatives
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概要
- 論文の詳細を見る
The scandium-catalyzed reactions of α-organosulfanyl and organoselanyl-α-fluoroacetates 1-2, acetamides 3-4 and acetonitrile 5 with soft nucleophiles proceeded to give the products 6a-b, 7a-c, 8a-c, 9a-e in good to high yields. We also successfully performed the scandium-catalyzed intramolecular cyclization reactions and obtained the unique 5-methylene-2-oxotetrahydropyrans 16-17.
- 公益社団法人日本薬学会の論文
- 2006-11-01
著者
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Yoshimatsu Mitsuhiro
Department Of Chemistry Faculty Of Education Gifu University
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Gotoh Kohei
Department Of Chemistry Faculty Of Education Gifu University
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Yamamoto Teruhisa
Department Of Chemistry Faculty Of Education Gifu University
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