Observation of a Low-viscosity Interface Between Immiscible Polymer Layers

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この論文は国立情報学研究所の電子図書館事業により電子化されました。研究会報告X-ray Photon Correlation Spectroscopy (XPCS) was employed in a surface standing wave geometry in order to resolve the thermally diffusive in-plane dynamics at both the surface/vacuum (top) and polymer/polymer (bottom) interfaces of a thin Polystyrene (PS) film on top of Poly (4-bromo styrene) (PBrS) and supported on a Si substrate. The top vacuum interface shows two relaxation modes: one fast and one slow, while the buried polymerpolymer interface shows a single slow mode. The slow mode of the top interface is similar in magnitude and wavevector dependence to the single mode of the buried interface. The dynamics are consistent with a low-viscosity mixed layer between the PS and PBrS and coupling of the capillary wave fluctuations between this layer and the PS.
物性研究刊行会の論文
2006-10-20