イミドゲルプレカーサーからのメソポーラスSi-B-Nセラミックスの合成(<ゲストエディターによる特集>有機-無機変換プロセス)

スポンサーリンク

概要

• 論文の詳細を見る

• A silicon boron imide gel BSi_3 (NH)_x (NH_2)_y (NMe_2)_z was prepared by an acid catalyzed ammonolysis of [tris (dimethylamino) silylamino] boron B [HNSi (NMe_2)_3]_3. Pyrolysis of the gel at 1000℃ under NH_3 flow leads to the formation of amorphous silicon boron nitride materials. All the gel and pyrolyzed products exhibit a mesoporous structure with a high-surface-area and narrow-pore-size distribution. The effective surface area of the pyrolyzed silicon boron nitride residues decreases with increasing temperature whereas the pore size of the residues increases as the temperature increases. The pyrolysis process was investigated by use of Fourier transform infrared spectra (FTIR), ^<29>Si and ^<11>B solid-state NMR and nitrogen adsorption analyses.

• 社団法人日本セラミックス協会の論文
• 2006-06-01

著者

• Cheng Fei

  Department Of Chemistry University Of Hull

• Cheng Fei

  Department Of Applied Chemistry School Of Science And Engineering Waseda University

• KELLY Stephen

  Department of Chemistry, University of Hull

• LEFEBVRE Frederic

  Laboratoire de Chimie Organometallique de Surface

• TOURY Berangere

  Department of Chemistry, University of Hull

• BRADLEY John

  Department of Chemistry, University of Hull

• Bradley John

  Department Of Chemistry University Of Hull

• Kelly Stephen

  Department Of Chemistry University Of Hull

• Toury Berangere

  Department Of Chemistry University Of Hull

関連論文

• イミドゲルプレカーサーからのメソポーラスSi-B-Nセラミックスの合成(有機-無機変換プロセス)
• Synthesis of a Soluble Precursor Possessing an Nb-N Backbone Structure and Its Pyrolytic Conversion into Niobium-Based Ceramics
• Preparation of a Soluble Precursor by an Aminolysis Reaction of Zr(NEt_2)_4 and Its Pyrolytic Conversion into ZrN
• Intraislet Regulation of Pancreatic Polypeptide Secretion in the Isolated Perfused Rat Pancreas
• 2. PROPE TOLERANCE WITH INDUCTION USING CAMPATH 1H AND LOW-DOSE CYCLOSPORIN MONOTHERAPY IN 31 CADAVERIC RENAL ALLOGRAFT RECIPIENTS(未来のための今 : 移植-次世紀への新たなるアプロ-チ)
• Surface Organometallic Chemistry of Tin:Grafting Reaction of Su(CH_3)_4 in HY Zeolite Supercage
• Surface Organometallic Chemistry of Tin : Grafting Reactions on Highly Dehydroxylated Silica

スポンサーリンク