High-Pressure Synthesis and Magnetic Properties of Orthorhombic CuRh_2O_4(Condensed Matter : Electronic Structure, Electrical, Magnetic and Optical Properties)
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概要
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Polycrystals of orthorhombic CuRh_2O_4 were prepared by a solid state reaction under high pressure and its magnetic properties were compared with those of polymorph-tetragonal CuRh_2O_4 (spinel-type compound). The orthorhombic phase undergoes antiferromagnetic transition at 24K. The ratio of the Curie-Weiss temperature (θ_<CW>) to the Neel temperature (T_N) is estimated to be f=|θ_<CW>|/T_N=2.6 and is considerably smaller than f in the tetragonal phase, 5.3. This indicates that geometrical magnetic frustration inherent in the Cu^<2+> network of the spinel structure is released in the orthorhombic phase with lower crystal symmetry. We observed a weak ferromagnetism below T_N in the orthorhombic phase; this is also discussed in terms of crystal symmetry.
- 社団法人日本物理学会の論文
- 2006-02-15
著者
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UEDA Y.
Institute of Pathology, Tenri Hospital
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YAGI T.
Institute for Solid State Physics, University of Tokyo
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Ohgushi K.
Institute For Solid State Physics University Of Tokyo
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GOTOU H.
Institute for Solid State Physics, University of Tokyo
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OHGUSHI K.
Institute for Solid State Physics, University of Tokyo
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