Active Carbon Supported Rhodium Catalyst in the Hydroformylation of 1-Hexene

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概要

• 論文の詳細を見る

• Hydroformylation performance of 1-hexene over rhodium solid catalyst was studied under mild reaction condition (H_2/CO=1/1, Pressure=3.0 MPa, T=403 K). Its hydroformylation activities were examined systematically in various solvents. Effects of operating variables on the CO conversion, yields of products and stability of the catalysts also have been discussed in detail. It was found that the rhodium catalyst exhibited the excellent activity in the n-octane solvent, while poor activity in the alcoholic and H_2O solvent. Rh/active carbon (Rh/C) catalyst presented superior catalytic performances over Rh/SiO_2 catalyst in the activity, selectivity and stability. As the most important, Rh/C catalyst showed stable activity in the continuous (olefin and synthesis gas) feeding system even in the low metal loading, giving the total turn over number (TON) of 500 during 14 hs reaction.

• 一般社団法人日本エネルギー学会の論文
• 2004-02-20

著者

• Asami Kenji

  北九州市立大

• Fujimoto K

  北九州市立大

• Fujimoto K

  Univ. Kitakyushu Kitakyushu Jpn

• FUJIMOTO KAORU

  School of Environmental Engineering, The University of Kitakyushu

• Fujimoto K

  University Of Kitakyushu

• 李 白涛

  中国科学院西安光机所

• Li Xiaohong

  北九州市立大

• LI Baitao

  Department of Applied Chemistry, School of Engineering, The University of Tokyo

• LI Xiaohong

  School of Environmental Engineering, The University of Kitakyushu

• ASAMI Kenji

  School of Environmental Engineering, The University of Kitakyushu

• Li Baitao

  Department Of Applied Chemistry School Of Engineering The University Of Tokyo

• Fujimoto Kaoru

  School Of Engineering The University Of Kitakyushu

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