Photoluminescence and Electroluminescence Characteristics of New Disubstituted Polyacetylenes : Optical Propertles of Condensed Matter
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概要
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Three di-substituted acetylenes in the tolane structure, 4-(trans-4-pentylcyclohexyl)-3',4'-difluorotolane (IM), 4-(trans4-heptylcyclohexyl)-4'-fluorotolane (2M), and 4-(4-pentylphenyl)-4'-fiuorotolane (3M), were polymerized in the presence of TaCl_5-based catalyst. The weight-average molecular weights Mw^^^→ of the polymers were high than 4 x l0^5. photoluminescence (PL) and electroluminescence (EL) of the three polymers made as single-layer device on indium-tin oxide glass (ITO), ITO/polymer/Al, have been comprehensively studied. By changing the structural conditions of polymer, such as introducing the fluorine atom or a long carbon chain to the end group of polymer side chains, the luminescence is clearly enhanced.
- 社団法人応用物理学会の論文
- 2001-09-15
著者
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Hsu Chain
Department Of Applied Chemistry National Chiao Tung University
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TING Ching
Department of Applied Chemistry, National Chiao Tung University
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Ting Ching
Department Of Applied Chemistry National Chiao Tung University