ニッケル及びパラジウム触媒を用いる高アトムエコノミー型新規環化付加反応の開発

概要

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In this review we report our development and applications of the highly selective cycloaddition reactions of unsaturated hydrocarbons such as conjugated enynes, electron-deficient allenes, and electron-deficient methylenecyclopropanes in the presence of nickel and palladium catalysts. Homocoupling reactions as well as co-cyclization reactions proceed with high atom economy, which is an attractive feature of these reactions. The efficient synthesis of 4-7 membered carbocycles was achieved.
公益社団法人日本薬学会の論文
2005-10-01