Formation of BaTiO_3 from a Barium Titanium Isopropoxide Complex
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概要
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The mechanism for the formation of BaTiO_3 from a single-crystal barium titanium isopropoxide complex with the presumed composition BaTi[OCH(CH_3)_2]_6・ C_6H_6 was investigated in this study. When the alkoxide complex was treated in Ar at 29℃ for 2.5 h, 80 wt% of the organic constituents in the crystal were eliminated as isopropanol, propene and benzene, thus forming BaTiO_3; 95 wt% of the organic constituents were eliminated in the same manner at a temperature below 100℃. The remaining organic constituents were eliminated as alkyl benzene at around 460℃ in Ar. Crystalline BaTiO_3 with ultrafine particles, ranging in size from 5 to 7.5 nm, formed even at room temperature under these experimental conditions.
- 社団法人応用物理学会の論文
- 1997-09-30
著者
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SUYAMA Yoko
Department of Materials Science, Faculty of Science and Engineering, Shimane University
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Noritake Tatsuo
Toyota Central Res. & Develop. Labs. Inc.
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NAGASAWA Mitsuru
Toyota Technological Institute
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Suyama Yoko
Department Of Materials Science Faculty Of Science & Engineering Shimane University
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Noritake Tatsuo
Toyota Central R&d Labs Inc.
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Suyama Yoko
Department of Applied Chemistry, Faculty of Engineering, Kyushu University
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