C-13 NMR and X-Ray Investigations of Phase Transitions in an Antiferroelectric Liquid Crystal
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概要
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We have investigated molecular motion and ordering in the smectic phases of a nonoriented antiferroelectric liquid crystal by means of C-13 NMR and powder X-ray diffraction. The marked line broadenings for core carbons observed by C-13 NMR indicate the existence of the characteristic molecular motion for the molecular core in the antiferroelectric chiral smectic C (SmC^*_A) phase. In the smectic phases appearing during the cooling and heating processes, local and overall molecular motions of each molecule observed by C-13 NMR are discussed in comparison with long-range order inside the layer observed by X-ray diffraction.
- 社団法人応用物理学会の論文
- 1992-07-01
著者
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Yoshizawa Atsushi
Material Development Research Laboratory Nippon Mining Co. Lid.
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Yoshizawa Atsushi
Materials Development Research Laboratories Nippon Mining Co. Ltd.
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Nishiyama Isa
Materials Development Research Laboratories Nippon Mining Co. Ltd.
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KIKUZAKI Hiroshi
Analytical Research Center, Nippon Mining Co., Ltd.
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ISE Noriko
Materials Development Research Laboratories, Nippon Mining Co., Ltd.
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Ise N
Japan Energy Corp. Saitama Jpn
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Kikuzaki Hiroshi
Analytical Research Center Nippon Mining Co. Ltd.
関連論文
- Different Effects of Alkyl Chain Length on Rotational Viscosity in Two Types of FLC Mixtures
- Antiferroelectric Chiral Smectic C Materials Having a 2-Alkyl Alkanoyl Group in the Chiral Part
- Effect of Alkyl Chain Length of Chiral Dopants on Rotational Viscosity of FLC Mixtures
- New Ferroelectric Liquid Crystal with Large Spontaneous Polarization
- Effect of Core Structure on Spontaneous Polarization in New Ferroelectric Liquid Crystals with a Fluorinated Chiral Part
- C-13 NMR and X-Ray Investigations of Phase Transitions in an Antiferroelectric Liquid Crystal
- ^C NMR Observation of Molecular Motions at the Smectic-A-Smectic-C (Smectic-C^*) Transition in a Recemic (Chiral) Smectic Liquid Crystal
- ^C NMR Analysis of Molecular Motions of a Ferroelectric Liquid Crystal