Molecular Orientation of Rubbed and Unrubbed Polyimide Films Determined by Polarized Infrared Absorption

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概要

• 論文の詳細を見る

• We have determined the orientations of poly[4,4'-oxydiphenylene-pyromellitimide] (PMDA-ODA) molecules in rubbed and unrubbed polyimide films (〜 120 Å) on Si substrates by polarized IR absorption spectroscopy. We found that for rubbed films the polymer chains are oriented along the rubbing direction and are tilted up on average by 8.5° from the surface plane. We conclude that the polymer chain inclination induced by rubbing determines the tilt of the director of the bulk liquid crystal.

• 社団法人応用物理学会の論文
• 1994-09-15

著者

• SAKAMOTO Kenji

  Research Institute of Electrical Communication, Tohoku University

• Sakamoto Kenji

  Research Institute Of Electrical Communication Tohoku University

• Arafune R

  Crest Japan Science And Technology Corporation

• Arafune Ryuichi

  Riken Photodynamics Research Center:(present Address)presto Japan Science And Technology Agency (jst

• Arafune Ryuichi

  Research Institute Of Electrical Communication Tohoku University

• SUZUKI Yasushi

  Technical Laboratory, Citizen Watch Co., Ltd.

• ITO Naoki

  Research Institute of Electrical Communication, Tohoku University

• USHIODA Sukekastu

  Research Institute of Electrical Communication, Tohoku University

• MOROKAWA Shigeru

  Technical Laboratory, Citizen Watch Co., Ltd.

• Ito Naoki

  Research Institute Of Electrical Communication Tohoku University

• Ushioda Sukekastu

  Research Institute Of Electrical Communication Tohoku University

• Suzuki Yasushi

  Technical Laboratory Citizen Watch Co. Ltd.

• Morokawa Shigeru

  Technical Laboratory Citizen Watch Co. Ltd.

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