Measurement of Evolved Hydrogen Volume during Anodization and Its Relationship to the Anodization Process
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It has been demonstrated that two hydrogen molecules evolve per dissolved silicon atom by anodization of silicon in HF solution, although a quantitative analysis has not been performed. The relationship of the volume evolved hydrogen atoms n_H during anodization of silicon in HF solution to several anodization conditions, dissolved silicon atoms n_<Si> and charges n_<hole> were demonstrated. In the case of a degenerated silicon substrate, four hydrogen atoms were released as two gas molecules when a silicon atom was dissolved. In the case of a nondegenerated silicon substrate, with an increated HF concentration, the number of hydrogen atoms evolved per dissolved silicon atom was than four, maintaining the relationship n_H+2.25n_<hole>=8.42n_<Si>. In this study, the relationship between the number of hydrogen atoms evolved and the silicon substrate resistivity was shown experimentally.
- 社団法人応用物理学会の論文
- 2000-02-15
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