Scaling of Time Variable and Constant Heating Rate Measurement
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概要
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In isothermal changes of physical quantities, the time variable t is frequently scaled by a characteristic time, τ. The scaling property of the time variable causes τq to become approximately constant for changes in the heating rate, q, of many orders of magnitude. This means that the activation energy can be derived from constant heating rate measurements. The case of a stretched exponential function is discussed in detail, and an example calculation is carried out for the cis-trans thermal isomerization of polyacetylene films.
- 社団法人応用物理学会の論文
- 1996-11-15
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