Time-of-Flight Pulsed Neutron Diffraction Study on Uniaxial Stress-Induced Domain Switching in LaNbO_4
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概要
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The domain orientation switching phenomena in the ferroelastlc material LaNbO_4 were observed by means of a time-of-flight neutron diffraction technique using a position-sensitive area detector. When stress is applied to the direction nearly perpendicular to (100) of one of the domains in the specimen, the a- and c-axes are easily transformed into the c-and a-axes of another domain, respectively. The domains with [001] nearly parallel to the stress direction do not switch orientation. Thus, the domain which occupied 34% of the specimen at the initial stage expanded up to 92% of the total volume by switching from other orientated domains. The estimated stress was 600gW/mm^2 at the final stage. The mechanism of switching orientation can structurally be interpreted by a small rotation and a small displacement of NbO_4 tetrahedra at the domain boundary which is a transient zone with a prototype structure.
- 社団法人応用物理学会の論文
- 1991-09-15
著者
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HORIUCHI Hiroyuki
Mineralogical Institute, Faculty of Science, University of Tokyo
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Horiuchi Hiroyuki
Mineralogical Institute Faculty Of Science University Of Tokyo
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KOBAYASHI Tadashi
School of Pharmacy, Hokuriku University
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SCHULTZ Arthur
Chemistry and Materials Science and Technology Divisions, Argonne National Laboratory
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Schultz Arthur
Chemistry And Materials Science And Technology Divisions Argonne National Laboratory
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Kobayashi Tadashi
School Of Pharmacy Hokuriku University
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