Phenomenologieal Thermodynamic Theory for Pb(Zn_<1/3>Nb_<2/3>)O_3-PbTiO_3 Binary Solid Solution and Calculations for Phase Diagram, Dielectric Constants, Lattice Parameters and Piezoelectric Constants : New Estimation Method for Unknown Dielectric Stiffne
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概要
- 論文の詳細を見る
Unknown dielectric stiffness constants in elastic Gibbs free energy for Pb(Zn_<1/3>Nb_<2/3>)O_3 were estimated by fitting the calculated phase diagram with the experimental one for the Pb(Zn_<1/3>Nb_<2/3>)O_3-PbTiO_3(PZN-PT) solid solution, and by considering the discontinuity of the dielectric constant at the rhombohedral-tetragonal morphotropic phase boundary in the (1-x)PZN-(X)PT system, x>0.105. The calculated PZN=PT phase diagram using the newly estimated values was in good agreement with the experimental PZN-PT one. The dielectric constants, lattice parameters and piezoelectric constants of the PZN-PT system could be calculated at a given composition and temperature. On comparison with experimental data, this method was found to be effective for material design.
- 社団法人応用物理学会の論文
- 1992-09-30
著者
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YAMAMOTO Takashi
Department of Cardiovascular and Respiratory Medicine, Shiga University of Medical Science
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Yamamoto Takashi
Department Of Cardiovascular And Respiratory Medicine Shiga University Of Medical Science
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Terashima Yoshihiro
Department Of Electrical Engineering National Defense Academy
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Yamamoto Takashi
Department Of Cardiology Tokushima Prefectural Central Hospital
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Yamamoto Takashi
Department Of Behavioral Physiology Graduate School Of Human Sciences Osaka University
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Yamamoto Takashi
Department Of Applied Chemistry Faculty Of Engineering Ehime University
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