Kinetics of Laser-Assisted Chemical Vapor Deposition of Tungsten Microstructures
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概要
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Tungsten microstructures (dots, strips and films) have been deposited via H_2 reduction of WF_6 on polycrystalline silicon-coated quartz substrates irradiated with a focused cw argon laser beam. The deposition rate of W dots, deduced from α-step measurements of the height of dots, was investigated as a function of irradiation time, composition of H_2-WF_6 gas mixtures and laser-induced surface temperature. At a laser-induced surface temperature ranging from 340° to 670℃ with an H_2 partial pressure varying from 50 to 700 Torr, the reaction order with respect to H_2 was equal to one-half, whereas at higher temperatures (750°-950℃) and lower H_2 partial pressures (20-80 Torr), the reaction order with respect to H_2 was found to be one. The reaction mechanism of the H_2 reduction of WF_6 on substrates irradiated with the argon laser beam is discussed.
- 社団法人応用物理学会の論文
- 1992-01-15
著者
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Auvert Geoffroy
Centre National D'etudes Des Telecommunications
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PAULEAU Yves
Institut National Polytechnique de Grenoble
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TONNEAU Didier
Societe Berin
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Pauleau Y
Enseeg Saint Martin D'herea Fra
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Tonneau D
Centre National De La Rech. Scientifique Meudon Fra