Development of New Cycloaddition Reactions Based on the Unique Reactivity of Unsaturated Hydrocarbons
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概要
- 論文の詳細を見る
We discovered that the reactivity of some conjugated and electron-deficient hydrocarbons was quite different in the presence of transition metal catalysts. In this review we report our development and applications of the highly selective palladium and nickel-catalyzed cycloaddition reactions of unsaturated hydrocarbons such as conjugated enynes, electron-deficient allenes, and electron-deficient methylenecyclopropanes. Some homocoupling reactions as well as co-cyclization reactions were described. The efficient synthesis of 4-7 membered carbocycles was achieved.
- 公益社団法人日本薬学会の論文
- 2005-09-01
著者
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SAITO SHINICHI
Department of Metabolism, Endocrinology and Molecular Medicine, Graduate School of Medicine, Osaka C
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Saito Shinichi
Department Of Chemistry Faculty Of Science Tokyo University Of Science
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Saito Shinichi
Department of Advanced Medicine for Uremia, Nagoya University School of Medicine
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