Copper (II) Complexes of the Schiff Bases derived from Chloramphenicol

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概要

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• Schiff bases (3,4) were obtained by condensation of D-threo-2-amino-1-(4-nitrophenyl)-1,3-propanediol (2) with salicylaldehyde and acetylacetone. Copper (II) chelates (5 and 6) were synthesized from 3 and 4,respectively, and their chemical structures were determined by elemental analysis, molecular weight measurement, and infrared and nuclear magnetic resonance spectroscopies. From the temperature dependence of their magnetic susceptibilities, 5,6 and the phenylcarbamate (7) derived from 5 were inferred to be tetramers having cubane-type structures. The phenylcarbamate (9) derived from 6 was presumed to have a dimeric structure.

• 公益社団法人日本薬学会の論文
• 1979-05-25

著者

• 中西 愛

  Faculty Of Pharmaceutical Sciences Kinki University

• 森 和亮

  Institute Of Chemistry College Of General Education Osaka University

• 厚地 妙子

  Faculty of Pharmaceutical Sciences, Kinki University

• 厚地 妙子

  Faculty Of Pharmaceutical Sciences Kinki University

関連論文

• Syntheses of Cyclic Hydroxamic Acid Derivatives, and Their Chelating Abilities and Biological Activities
• Syntheses and Anti-Inflammatory and Analgesic Activities of Hydroxamic Acids and Acid Hydrazides
• Copper (II) Complexes of the Schiff Bases derived from Chloramphenicol
• Syntheses and Antimicrobial Activities of Five-Membered Heterocycles Having a Phenylazo Substituent

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