Synthesis of Nitro Compounds by Means of Oxidation of Acylamino Compounds. X. Reinvestigation of Reaction Conditions of Oxidation of Acylamino Compounds to Nitro Compounds.
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概要
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Acylarylamino compounds having chloro or methoxyl group at meta-or para-position of benzene ring were oxidized with hydrogen peroxide in varied conditions. In the case of introduction of electron-attracting group, yields of nitro compounds were fairly good and at the same time, considerable amounts of the starting materials were recovered, while, in the case of electron-releasing group, yields of nitro compounds were poor and almost none of the starting materials was recovered. Reasonable explanations of these phenomena were discussed.
- 公益社団法人日本薬学会の論文
- 1964-03-25
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