Synthesis of the Compounds Containing Grisan Ring.

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概要

• 論文の詳細を見る

• 4-(o-Methoxymethoxybenzoyl)-1,3-cyclohexanedione, having a β-tricarbonyl system, was synthesized by the interaction of disodio-1,3-cyclohexanediene and methyl o-methoxymethoxybenzoate in liquid ammonia. 4-(o-Hydroxybenzoyl)-1,3-cyclohexanedione, having a hypothetical β-tetracarbonyl system, was also prepared. Grisan-2', 3,4'-trione yielded from the β-tetraketone by means of alkaline ferricyanide oxidation. The structures of its two isomeric methyl enol ethers were proved by deriving them to grisan-2', 3-and grisan-3,4'-dione.

• 社団法人日本薬学会の論文
• 1964-02-25

著者

• 田中 雅

  Osaka Research Laboratory, Tanabe Seiyaku Co., Ltd.

• 田中 雅

  Osaka Research Laboratory Tanabe Seiyaku Co. Ltd.

関連論文

• Structures of Norsecurinine and Dihydronorsecurinine
• Absolute Stereochemistry at C_ of Norsecurinine and Dihydronorsecurinine
• Structure and Stereochemistry of Norsecurinine and Dihydronorsecurinine
• Synthesis of the Compounds Containing Grisan Ring.

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