One-pot Enantioselectiev Synthesis of Optically Active Homoalylic Alcohols from Allyl Halides
スポンサーリンク
概要
- 論文の詳細を見る
A one-pot, convenient method for the preparation of optically active homoallylic alcohols from allyl halides was developed. Allyltrichlorosilanes were generated in situ from allyl halides and trichlorosilane in the presence of cuporous chloride and tertiary amine. Without isolation of the allyltrichlorosilanes, benzaldehyde and chiral biquinoline N, N'-dioxide were introduced into the same flask, producing the corresponding homoallylic alcohols with good to high enantioselectivities.
- 社団法人日本薬学会の論文
- 2000-02-01
著者
-
Saito Makoto
Graduate School of Enginnering, University of Miyazaki
-
Hashimoto S
Graduate School Of Pharmaceutical Sciences Hokkaido University
-
KANAJIMA Makoto
Graduate School of Pharmaceutical Sciences, Hokkaido University
-
HASHIMOTO Shunichi
Graduate School of Pharmaceutical Sciences, Hokkaido University
-
Hashimoto Shunichi
Graduate School Of Pharmaceutical Sciences Hokkaido University
-
Kanajima Makoto
Graduate School Of Pharmaceutical Sciences Hokkaido University
-
Saito M
Graduate School Of Pharmaceutical Sciences Hokkaido University
関連論文
- A Space Lower-Bound Technique for Three-Dimensional Alternating Turing Machines
- On Empirical Implications of Highly Interest-Elastic Money Demand : A Note
- One-pot Enantioselectiev Synthesis of Optically Active Homoalylic Alcohols from Allyl Halides
- P-26 CATALYTIC ENANTIOSELECTIVE SYNTHESIS OF (-)-METAZOCINE
- P-16 ENANTIOSELECTIVE SYNTHESIS OF TETRAHYDROPYRAN NATURAL PRODUCTS EXPLOITING DIRHODIUM (II)-CATALYZED HETERO-DIELS-ALDER REACTION
- P-225 CHIRAL PHOSPHINE OXIDE BINAPO AS AN ORGANOCATALYST FOR THE ENANTIOSELECTIVE ALLYLATION AND ALDOL REACTION
- Practical Synthesis of Dirhodium (II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]
- A Concise and Enantioselective Synthesis of a C-6 O-Acyl Side Chain Equivalent of Zaragozic Acid A
- Aerobic Oxidative Coupling of 2-Naphthol Derivatives Catalyzed by a Copper-Amine Complex without Solvent
- Inhibition of Salvage Synthesis of Nucleic Acid by Adenosine 3', 5'-Cyclic Decylphosphoramidate in Mastocytoma P-815 Cells
- EFFECT OF ADENOSINE 3', 5'-CYCLIC MONOPHOSPHATE DERIVATIVES ON ACUTE LIVER INJURY INDUCED BY CARBON TETRACHLORIDE
- Cytotoxic Effect of 8-Amino Adenosine 3', 5'-Cyclic Monophosphate on FM3A Mouse Mammary Tumor Cells