Synthesis and Structure Studies of Complexes of Some Second Row Transistion Metals with 1-(Phenylacetyl and Phenoxacetyl)-4-phenyl-3-thiosemicarbazide

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概要

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• THe synthesis of the new complexes of 1-phenylacetyl-4-phenyl-3-thiosemicarbazide (H_2papts) and 1-phenoxyacetyl-4-phenyl-3-thiosemicarbazide (H_2p_xapts); [Ru(HL)_2(H_2O)_2], [Rh(HL)_3], [Ag(H_2L)(H_2O)_2](NO_3), trans [UO_2(HL)(bipy)(AcO)(H_2O_2)] (H_2L=H_2papts, H_2p_xapts; bipy=2,2'-bipyridyl), [Ag(H_2papts)(bipy)]^+ and [Pd-(Hpapts)(bipy)]^+ is described. Characterization of these complexes by IR, electronic and ^1H-NMR sectra, conductometric titrations and thermal analysis is included. The complexes [Ru(HL)_2(H_2O)_2] were found to be efficient catalysts for the oxidation of primary alcohols to aldehydes and acids, secondary alcohols to ketones and aryl halides to aldehydes and acids in the presence of NaIO_4 as co-oxidant.

• 公益社団法人日本薬学会の論文
• 2000-02-01

著者

• Mostafa Sahar

  Chemistry Department Faculty Of Science Mansoura University

• BEKHEIT Magdy

  Chemistry Department, Faculty of Science, Mansoura University

• Bekheit M

  Chemistry Department Faculty Of Science Mansoura University

• Bekheit Magdy

  Chemistry Department Faculty Of Science Mansoura University

関連論文

• Synthesis and Structure Studies of Complexes of Some Second Row Transistion Metals with 1-(Phenylacetyl and Phenoxacetyl)-4-phenyl-3-thiosemicarbazide
• Mononuclear and Polynuclear Chelates of Picolinoyldithiocarbazate

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