NOVEL CAGE COMPOUNDS FROM THE REACTIONS OF THIAZOLIUM N-METHYLIDES WITH METHYLENECYCLOPROPENES

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概要

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• Thiazolium N-dicyanomethylide and N-phenacylide reacted with methylenecyclopropenes bearing a carbonyl functional group at the 4-position in THF to give novel cage compounds arising from an intramolecular cyclization of the initially formed endo-[3+2] cycloadducts. Although the reaction of the N-dicyanomethylide with a methylenecyclopropene having two cyano groups at the 4-position in THF gave no adduct, the same reaction in an alcohol afforded a cage compound incorporated with the alcohol.

• 公益社団法人日本薬学会の論文
• 1982-05-25

著者

• 柘植 乙彦

  Research Institute Of Industrial Science Kyushu University 86

• 下原田 洋

  Research Institute of Industrial Science, Kyushu University 86

• 下原田 洋

  Research Institute Of Industrial Science Kyushu University 86

関連論文

• NOVEL CAGE COMPOUNDS FROM THE REACTIONS OF THIAZOLIUM N-METHYLIDES WITH METHYLENECYCLOPROPENES

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