Photolysis of Aldrin in the Presence of Benzaldehyde in a Solid-Vapor-Air System

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概要

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• Aldrin (1) was found to undergo epoxidation and isomerization, when irradiated at wavelengths longer than 290 nm in the presence of benzaldehyde in air, to give dieldrin (2) and photoaldrin (1,1,2,3,3a, 7a, -hexachloro-2,3,3a, 3b, 4,6a, 7,7a-octahydro-2,4,7-metheno-1H-cyclopenta[a]pentalene, 3), respectively, followed by isomerization or epoxidation, respectively, to afford photodieldrin (1,1,2,3,3a, 7a-hexachloro-5,6-epoxy-decahydro-2,4,7-metheno-1H-cyclopenta[a]pentalene, 4) in each case. The predominant photo-products were the epoxides, 2 and 4. These photo-products were also formed when a mixture of 1 and benzaldehyde in air was exposed to sunlight.

• 公益社団法人日本薬学会の論文
• 1996-08-15

著者

• Nojima Kazuhiro

  Faculty Of Pharmaceutical Sciences Josai University

• ISOGAMI Chiho

  Faculty of Pharmaceutical Sciences, Josai University

• Isogami C

  Faculty Of Pharmaceutical Sciences Josai University

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• Reactions of Polymethylphenols, Polychlorophenols and Polynitrophenols with Chloramine and Formation of Cyanogen Chloride (Proceedings of the 12 th Symposium on Environmental Pollutants and Toxicology) (Regular Presentations)
• Studies on Photochemical Reactions of Air Pollutants. XIV. Photooxidation of Sulfur Dioxide in Air by Various Air Pollutants
• Studies on Photochemical Reactions of Air Pollutants. XV. Photoreactivity of Heptachloro-3'-cyclopentenyldioxy Heptachloro-2-cyclopentene Formed by Exposure of Hexachlorocyclopentadiene to Ultraviolet Light in Air
• Photolysis of Aldrin in the Presence of Benzaldehyde in a Solid-Vapor-Air System

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