PRACTICAL TOTAL SYNTHESES OF (R)-(+)- AND (S)-(-)-14-HYDROXY-4,14-RETRO-RETINOL

概要

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Practical and facile total syntheses of the remarkably unstable (R)-(+)-14-hydroxy-4,14-retro-retinol [(R)-14HRR] 1 and of its enantiomer 2 have been achieved via an acid-catalyzed dehydration reaction of the respective tetraeneol intermediates 10 and its enantiomer obtained from (R)-(+)-1,2-O-isopropylidene-butane-1,2,3-triol 3.
公益社団法人日本薬学会の論文
1994-07-15