Structure of μ-Oxo-tetranuclear Copper(II) Complex Produced from Chlorpromazine (cpz) and Cu(II)Cl_2. An Alternative Binding Site of the cpz Molecule to Metal
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概要
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The structure of the complex [Cu_4OCl_6(cpz)_4](C_6H_6)_6,produced from the reaction between chlorpromazine (cpz) and Cu(II)Cl_2 in the presence of a small amount of water, was determined by X-ray diffraction analysis. The complex crystallizes in the monoclinic space group P2_1/a with a=66.807(3), b=16.767(2), c=9.6484(4)Å, β=95.725(3)゜, V=10754(1)Å^3,and Z=4. Each copper atom in the core (Cu_4OCl_6) is coordinated by a cpz ligand through the terminal nitrogen atom of the side-chain.
- 1994-02-15
著者
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中川 弘子
城西大学
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川面 博司
Faculty of Pharmaceutical Sciences, Josai University
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山田 紘一
城西大学
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山田 紘一
Faculty of Pharmaceutical Sciences, Josai University
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尾熊 永至
Faculty of Pharmaceutical Sciences, Josai University
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中川 弘子
Faculty of Pharmaceutical Sciences, Josai University
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川面 博司
Faculty Of Pharmaceutical Sciences Josai University
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尾熊 永至
Faculty Of Pharmaceutical Sciences Josai University
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