Studies on the Oxidative Addition of N, N-Dimethylamine to Bromojuglones and Bromomethyljuglones

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概要

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• The nucleophilic addition of dimethylamine to bromojuglones and bromomethyljuglones is followed by elimination of hydrogen bromide or oxidation. With 2-bromojuglone, the oxidative process predominates at low temperature. The regiochemistry of the addition is a function of the temperature and of the position of the bromine atom (C-2 or C-3) on the quinone.

• 公益社団法人日本薬学会の論文
• 1994-11-15

著者

• Fillion Houda

  Laboratoire De Chimie Organique Faculte De Pharmacie Universite Claude Bernard Lyon

• Fillion Houda

  Laboratoire De Chimie Organique

• PAUTET Felix

  Laboratoire de Chimie Organique Institut des Sciences Pharmaceutiques et Biologiques

• CHAKER Leila

  Laboratoire de Chimie Organique, Institut des Sciences Pharmaceutiques et Biologiques

• Chaker Leila

  Laboratoire De Chimie Organique Institut Des Sciences Pharmaceutiques Et Biologiques

関連論文

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• Generation of a Thiazole o-Quinodimethane from an Imino Derivative and Its Intermolecular Diels-Alder Trapping with Alkynes or Quinones
• Studies on the Oxidative Addition of N, N-Dimethylamine to Bromojuglones and Bromomethyljuglones
• Synthesis of Furnaphth[1,3]oxazine and Furo[1,3]oxazinoquinoline Derivatives as Precursors for an o-Quinonemethide Structure and Potential Antitumor Agents
• Synthesis of Mannich Bases of 5-Hydroxynaphthalene-1,8-carbolactone as Potential Antifungal or Antitumor Agents
• Reactivity of an o-Indoloquinone to 1-and 2-Azadienes

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