α-Vetivone

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概要

• 論文の詳細を見る

• The structure of α-vetivone, one of the major odoriferous principles of vetiver oil had previously been accepted as being represented by Ia. Air oxidation of α-vetivone in the presence of 1N t-butoxide yielded, after treatment with p-toluenesulphonic acid, a conjugated dienedione VII. The enantiomeric compound was prepared, by oxidation, from the structurally well-established eremophilone XII, thus requiring that the structure of α-vetivone be revised to II. Some interesting observations were made with regards ORD and CD measurements in comparison with curves obtained from cholest-4-en-3-one. Biogenetic relationships between some related compounds are also discussed.

• 公益社団法人日本薬学会の論文
• 1969-07-25

著者

• 遠藤 勝也

  Department Of Chemistry University Of Western Ontario

• MAYO PAULDE

  Department of Chemistry, University of Western Ontario

• Mayo Paulde

  Department Of Chemistry University Of Western Ontario

関連論文

• Configuration of Widdrol
• α-Vetivone

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