Studies on Metal Chelate Compounds of Phenazine Derivatives. II. Spectrophotometric Studies on Copper Chelate Compounds of 1,6-Dihydroxyphenazine and its Di-N-oxide, Iodinin.
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Copper chelates of 1,6-dihydroxyphenazine and its di-N-oxide, which possess two functional groups, were examined by spectrophotometric method concerning their properties and compositions in solution, as well as their dissociation constants. 1,6-Dihydroxyphenazine forms a five-membered chelate ring, indicating the molar ratio of 1 : 1,a normal complex. The N-oxide derivative also form a chelate with molar ratio of 1 : 1,forming a six-membered chelate ring.
- 公益社団法人日本薬学会の論文
- 1958-10-15
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