Enantioselective [2,3] Sigmatropic Rearrangement of α-Propargyloxyacetic Acids Mediated by BuLi-(-)-Sparteine Complex

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概要

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• The [2,3] sigmatropic rearrangement of α-propargyloxyacetic acids was achieved by the use of BuLi-(-)-sparteine complex in toluene. BuLi-chiral ligand complexes are stronger bases than lithium amides, so they are expected to be good mediators of this reaction.

• 公益社団法人日本薬学会の論文
• 1998-02-15

著者

• Manabe Shino

  Faculty Of Pharmaceutical Sciences University Of Tokyo:(present Address)the Institute Of Physical An

• Manabe S

  Riken (the Institute Of Physical And Chemical Research)

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• Enantioselective [2,3] Sigmatropic Rearrangement of α-Propargyloxyacetic Acids Mediated by BuLi-(-)-Sparteine Complex

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