The Photochemistry of Metyrapone in the Solid State

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概要

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• Metyrapone (2-methyl-1,2-di-3-pyridyl-1-propanone) undergoes α-cleavage upon irradiation in the solid state. The reaction occurs at the crystal surface, and the radicals formed in part recombine to give dipyridylketones, and in part add oxygen to give nicotinic acid and 3-(1-hydroxymethylethyl)pyridine. The crystals partially melt and the reacton continues until complete decomposition of the starting material.

• 公益社団法人日本薬学会の論文
• 1997-02-15

著者

• Albini A

  Univ. Pavia Pavia Ita

• FASANI Elisa

  Department of Organic Chemistry, University of Pavia

• MELLA Mariella

  Department of Organic Chemistry, University of Pavia

• ALBINI Angelo

  Department of Organic Chemistry, University of Pavia

• Fasani E

  Univ. Pavia Pavia Ita

• Mella Mariella

  Department Of Organic Chemistry University Of Pavia

関連論文

• The Photochemistry of Metyrapone in the Solid State

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