SPECTROPHOTOMETRIC DETERMINATION OF TIN(IV) WITH PHENYLFLUORONE AND DODECYLTRIMETHYLAMMONIUM BROMIDE
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概要
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The sensitizing effect of dodecyltrimethylammonium bromide (DTMAB) on the spectrophotometric determination of tin(IV) with phenylfluorone was studied. Under the optimum conditions the sensitivity was about twice as high as that without DTMAB. The calibration curve was linear up to 0.20 ppm of tin(IV) . Polyvinyl alcohol (PVA), a commonly used dispersant, was not necessary. Metal ions such as Fe^<3+>, Fe^<2+>, Si, As^<5+>, As^<3+>, Pb^<2+>, Cu^<2+>, Sb^<3+>, and Bi^<3+> did not interfere with the determination, while Ge^<4+> gave a positive error.
- 1984-06-05
著者
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Kuwabara Hiroko
Department Of Industrial Chemistry Gunma Technical College
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Kurihara Hideya
Department of Industrial Chemistry, Gunma Technical College
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