液液界面におけるパラジウム(II)-ピリジルアゾ錯体の生成と会合(博士論文要録)

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概要

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• The complexation and aggregation reactions of a palladium (II)-pyridylazo complex (PdL) at the liquid-liquid interface were investigated by means of conventional and new methods, and new-type isomer recognizing reactions of diazine derivatives with PdL by complexation and aggregation at the liquid-liquid interface were proposed in this thesis. Their isomer recognizing reactions were not observed in a homogeneous system, and the specificity of the liquid-liquid interface as a reaction field has been revealed. These results developed a new function of the liquid-liquid interface as an analytical and synthetic field. Moreover, a new microscopic method, named centrifugal liquid membrane-resonance Raman microprobe spectroscopy (CLM-RRMS), was proposed, and its advantage for measuring interfacial species was revealed. This method permitted a selective observation of the Raman spectra for the interface and bulk phases in the CLM system and time-resolved measurements of the interfadal reaction by resonance Raman scattering for the first time. The combination of the new method and the conventional method, such as the CLM method and the high-speed stirring method, allowed us to obtain much structural information about PdL adsorbed at the liquid-liquid interface and to understand the property of the liquid-liquid interface.

• 社団法人日本分析化学会の論文
• 2003-10-05

著者

• 大橋 朗

  茨城大学理学部

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