Mg Intercalation and Ca Substitution for Bi in (BiS)_<1+x> (TiS_2)_n (n=1 and 2)
スポンサーリンク
概要
- 論文の詳細を見る
Tlae electron-energy-loss spectr'oscopy (EELS) spectr'at of' (C?r..Bi) .,S));.TiS,z (x t 0.5 ?rndy Z 0.2) anad IIN ' Ig.(BuS))?.(TiSz),z (r IC; 0.04- 0.07) ;tre uneatstnred to sttrdy ?rlkatline e;tr'th naetstlsttbstuttrtuon arad intercatlartion efl'ects err the electronic strtucttrr'e of' Blue first- ?tuad the second-staoebtaaisfit-lst'yzer' cotaapotrnds cont?tinirag Bi. It is f'ottnd thaat atltluotrgh 21 loss peatlc ?trising frotau 21 patrtialplasntaa resoraatruce in a TiS3 latyer us still obser'x'ed ;tf'ter lstrge sc?tle Cat strlostitution for Bi in 21 BiSl;tyer, the electronic strtrcttrre atad ojctical jcroperties 21IC ?tf['ected 111014) sigrrific?xrntly tln?tn tlaose ofthe lN?Ig intercal?rtion derixvzttixve of time secotud-st?tge cottapotmnd. Kraataaers-Kronig (K-K) 2[Il2llYS(28show that energy stattes f'or Clue C?t strbstittrtion cotaajcotrnd are 1110F(2 delocalizecl ?rnd flue ojcticatlxvitadoxv arotruud 7.5 eV, xx'laicl? hats l.>eeua f'otutad for lotrlk TiS.z, disatjojce?trs. Fc>r t1?e .N4g intercatlattioncoutapotrrad the.joint density of' st?ries (JDS) is S112111)Cl' dtre to arm iuacr'e?tsed d / p eraergy g2l1]) ?rnd /orthe locatlization of' enen'gy st?ries in 21 direction perjcendictulstr to lad ' ers.
- 1999-09-15
著者
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OHNO Youichi
Department of Electrical and Electronic Engineering,Faculty of Engineering,Utsunomiya University
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Ohno Youichi
Department Of Applied Physics Faculty Of Engineering Utsunomiya University
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Ohno Youichi
Department Of Electrical And Electronic Engineering Faculty Of Engineering Utsunomiya University
関連論文
- Mg Intercalation and Ca Substitution for Bi in (BiS)_ (TiS_2)_n (n=1 and 2)
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- X-Ray K-Absorption Spectra and Electronic Structures of Vanadium Hydrides and Deuterides
- Scanning Tunneling Microscopy, X-Ray Photoelectron Spectroscopy and Electron Energy-Loss Spectroscopy Studies of the Misfit Layer Compounds {(Pb_Sb_xS)_}mTS 2 (T=Ti and Nb; m=1 and 2)
- Breakdown of Dipole Selection Rules in Electron-Excited 3p-3d Transitions within Localized Transition-Metal Ions at Low Incident Energies
- Raman and Infrared Spectra of Misfit Layer Compounds MNbS_3 (M=Sn, Pb, La, Ce)