Hydration Thermodynamics of Biomolecules : I. Transfer Free Energy of Solutes with Variable Conformations
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概要
- 論文の詳細を見る
A theoretical analysis is presented on the free energy of transfer from a solvent including vacuum to another one for solute molecules with variable conformations. Allthe interactions concerned in the transfer free energy are shown to be classified intotwo groups different in their nature: The one is composed of the intramolecular in-teractions of solutes where the shielding effect of solvent is included, and the otherconsists of various solvation effects characteristic of constituent atoms of each solute.Several assumptions implicitly taken in conventional analyses of the free energy oftransfer between different solvents, are explicitly shown. It is described that formulasderived in this work will serve to determine more accurate atounic parameters on thesolvation thermodynamics of biomolecules by comparison with experimental data.
- 社団法人日本物理学会の論文
- 1990-11-15
著者
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Soda Kunitsugu
Department Of Science And Mathematics Nagoya University Of Technology
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Soda Kunitsugu
Department Of Bioengineering Faculty Of Engineering Nagaoka University Of Technology
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Hirashima Hitoshi
Department Of Bioenigineering Nagaoka University:kikkoman Corporation
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Hirashima Hitoshi
Department Of Science And Mathematics Nagoya University Of Technology
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