A Tricritical Point in a Model Two-Component System of Enantiomers
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概要
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A lattice gas is studied in which the two enantiomeric forms of a molecule (d and l)are adsorbed onto a triangular lattice. The phase cliagram is investigated using a Gug-genheim-McGlashan approximation with two order parameters. For a range of intermolecular interactions, such as may occur between the zwitterion forms of an aminoacid, the system is found to exhibit a tricritical point at which a d-rich phase, an /-richphase, and a racemic phase simultaneously become a single phase.tricritical point, lattice gas:, enantiorners
- 社団法人日本物理学会の論文
- 1989-02-15
著者
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Dale A.
Department Of Chemistry Texas Christian University
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Shinmi Masato
Department of Chemistry,Texas Christian University
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Huckaby Dale
Department of Chemistry,Texas Christian University
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Shinmi Masato
Department Of Chemistry Texas Christian University
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Huckaby Dale
Department of Chemistry, Texas Christian University